The synergistic flame-retardant behaviors of soybean oil phosphate-based polyols and modified ammonium polyphosphate in polyurethane foam

The synergistic flame-retardant behaviors of soybean oil phosphate-based polyols and modified ammonium polyphosphate in polyurethane foam

Full description

Bibliographic Details
Published in:Journal of polymer research. - Springer Netherlands, 1994. - 30(2023), 2 vom: 25. Jan.
Main Author: Chi, Junrui (Author)
Other Authors: Zhang, Yu (Author) Tu, Fanbin (Author) Sun, Junchen (Author) Zhi, Huizhen (Author) Yang, Jinfei (Author)
Format: electronic Article
Language:English
Published: 2023
ISSN:1572-8935
External Sources:lizenzpflichtig
LEADER 01000naa a22002652 4500
001 OLC213355727X
003 DE-627
005 20230506160338.0
007 cr uuu---uuuuu
008 230506s2023 xx |||||o 00| ||eng c
024 7 |a 10.1007/s10965-023-03447-6  |2 doi 
035 |a (DE-627)OLC213355727X 
035 |a (DE-He213)s10965-023-03447-6-e 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
082 0 4 |a 540  |q VZ 
084 |a 35.00$jChemie: Allgemeines  |2 bkl 
100 1 |a Chi, Junrui  |e verfasserin  |4 aut 
245 1 0 |a The synergistic flame-retardant behaviors of soybean oil phosphate-based polyols and modified ammonium polyphosphate in polyurethane foam 
264 1 |c 2023 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a © The Polymer Society, Taipei 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. 
520 |a Abstract Vegetable oils, as raw materials for polyurethane foam, have attracted much attention for being non-toxic, biodegradable, renewable, and so on. However, polyurethane foam burns extremely easily and the vegetable oil grafted phosphorus/silicon flame retardant polyols alone do have insufficient fire-retardant efficiency. Herein, a new bio-based flame retardant (Polyol-P) was successfully synthesized through a ring-opening reaction by using epoxy soybean oil and phenylphosphonic acid as raw materials. Then, Polyol-P was first combined with melamine-formaldehyde resin-microencapsulated ammonium polyphosphate (MAPP) to modify polyurethane foam. The synergistic flame-retardant effects of Polyol-P with MAPP in polyurethane foam have been studied by thermogravimetric analysis, limiting oxygen index test, vertical burning test, and cone calorimeter. TG test results showed the addition of Polyol-P and MAPP promoted the degradation of polyurethane foam composites and the char residue rate at 800 °C of PU-P/15MAPP was significantly enhanced. Flame retardant test results confirmed PU-P/15MAPP exhibited LOI of 25.8% and passed the V-0 rating in the UL-94 test. Cone calorimeter test results indicated the peak heat release rate of PU-P and PU-P/15MAPP reduced from 395.10 kW/$ m^{2} $ to 291.92 kW/$ m^{2} $ and 222.72 kW/$ m^{2} $ compared with PU-0. Furthermore, the ratio of CO and $ CO_{2} $ remarkably reduced and the residual carbon yield of PU-P/15MAPP was the highest, and its value was 20.0 wt%. SEM confirmed that the char residue of PU-P/15MAPP was wrinkled and uneven, which was caused by the release of many volatile gases. FT-IR verified the formed structure of the phosphorous-containing carbonaceous structure. These results suggest that Polyol-P and MAPP have a good synergistic flame retardancy on polyurethane composites and can reduce fire risk. 
650 4 |a Soybean oil 
650 4 |a Ammonium polyphosphate 
650 4 |a Rigid polyurethane foam 
650 4 |a Flame retardant 
700 1 |a Zhang, Yu  |4 aut 
700 1 |a Tu, Fanbin  |4 aut 
700 1 |a Sun, Junchen  |4 aut 
700 1 |a Zhi, Huizhen  |0 (orcid)0000-0002-8812-1629  |4 aut 
700 1 |a Yang, Jinfei  |4 aut 
773 0 8 |i Enthalten in  |t Journal of polymer research  |d Springer Netherlands, 1994  |g 30(2023), 2 vom: 25. Jan.  |h Online-Ressource  |w (DE-627)340872098  |w (DE-600)2065616-6  |w (DE-576)121466671  |x 1572-8935  |7 nnns 
773 1 8 |g volume:30  |g year:2023  |g number:2  |g day:25  |g month:01 
856 4 0 |u https://dx.doi.org/10.1007/s10965-023-03447-6  |z lizenzpflichtig  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_OLC 
912 |a GBV_ILN_11 
912 |a GBV_ILN_20 
912 |a GBV_ILN_22 
912 |a GBV_ILN_23 
912 |a GBV_ILN_24 
912 |a GBV_ILN_31 
912 |a GBV_ILN_32 
912 |a GBV_ILN_39 
912 |a GBV_ILN_40 
912 |a GBV_ILN_60 
912 |a GBV_ILN_62 
912 |a GBV_ILN_63 
912 |a GBV_ILN_69 
912 |a GBV_ILN_70 
912 |a GBV_ILN_73 
912 |a GBV_ILN_74 
912 |a GBV_ILN_90 
912 |a GBV_ILN_95 
912 |a GBV_ILN_100 
912 |a GBV_ILN_101 
912 |a GBV_ILN_105 
912 |a GBV_ILN_110 
912 |a GBV_ILN_120 
912 |a GBV_ILN_138 
912 |a GBV_ILN_150 
912 |a GBV_ILN_151 
912 |a GBV_ILN_152 
912 |a GBV_ILN_161 
912 |a GBV_ILN_170 
912 |a GBV_ILN_171 
912 |a GBV_ILN_187 
912 |a GBV_ILN_206 
912 |a GBV_ILN_213 
912 |a GBV_ILN_224 
912 |a GBV_ILN_230 
912 |a GBV_ILN_250 
912 |a GBV_ILN_281 
912 |a GBV_ILN_285 
912 |a GBV_ILN_293 
912 |a GBV_ILN_370 
912 |a GBV_ILN_602 
912 |a GBV_ILN_636 
912 |a GBV_ILN_702 
912 |a GBV_ILN_2001 
912 |a GBV_ILN_2003 
912 |a GBV_ILN_2004 
912 |a GBV_ILN_2005 
912 |a GBV_ILN_2006 
912 |a GBV_ILN_2007 
912 |a GBV_ILN_2008 
912 |a GBV_ILN_2009 
912 |a GBV_ILN_2010 
912 |a GBV_ILN_2011 
912 |a GBV_ILN_2014 
912 |a GBV_ILN_2015 
912 |a GBV_ILN_2020 
912 |a GBV_ILN_2021 
912 |a GBV_ILN_2025 
912 |a GBV_ILN_2026 
912 |a GBV_ILN_2027 
912 |a GBV_ILN_2031 
912 |a GBV_ILN_2034 
912 |a GBV_ILN_2037 
912 |a GBV_ILN_2038 
912 |a GBV_ILN_2039 
912 |a GBV_ILN_2044 
912 |a GBV_ILN_2048 
912 |a GBV_ILN_2049 
912 |a GBV_ILN_2055 
912 |a GBV_ILN_2056 
912 |a GBV_ILN_2057 
912 |a GBV_ILN_2059 
912 |a GBV_ILN_2061 
912 |a GBV_ILN_2064 
912 |a GBV_ILN_2065 
912 |a GBV_ILN_2068 
912 |a GBV_ILN_2088 
912 |a GBV_ILN_2093 
912 |a GBV_ILN_2106 
912 |a GBV_ILN_2107 
912 |a GBV_ILN_2108 
912 |a GBV_ILN_2110 
912 |a GBV_ILN_2111 
912 |a GBV_ILN_2112 
912 |a GBV_ILN_2113 
912 |a GBV_ILN_2118 
912 |a GBV_ILN_2119 
912 |a GBV_ILN_2129 
912 |a GBV_ILN_2134 
912 |a GBV_ILN_2136 
912 |a GBV_ILN_2143 
912 |a GBV_ILN_2144 
912 |a GBV_ILN_2147 
912 |a GBV_ILN_2148 
912 |a GBV_ILN_2152 
912 |a GBV_ILN_2153 
912 |a GBV_ILN_2188 
912 |a GBV_ILN_2190 
912 |a GBV_ILN_2232 
912 |a GBV_ILN_2336 
912 |a GBV_ILN_2433 
912 |a GBV_ILN_2446 
912 |a GBV_ILN_2470 
912 |a GBV_ILN_2474 
912 |a GBV_ILN_2507 
912 |a GBV_ILN_2522 
912 |a GBV_ILN_2548 
912 |a GBV_ILN_4035 
912 |a GBV_ILN_4037 
912 |a GBV_ILN_4046 
912 |a GBV_ILN_4112 
912 |a GBV_ILN_4125 
912 |a GBV_ILN_4126 
912 |a GBV_ILN_4242 
912 |a GBV_ILN_4246 
912 |a GBV_ILN_4249 
912 |a GBV_ILN_4251 
912 |a GBV_ILN_4305 
912 |a GBV_ILN_4306 
912 |a GBV_ILN_4307 
912 |a GBV_ILN_4313 
912 |a GBV_ILN_4322 
912 |a GBV_ILN_4323 
912 |a GBV_ILN_4324 
912 |a GBV_ILN_4325 
912 |a GBV_ILN_4326 
912 |a GBV_ILN_4328 
912 |a GBV_ILN_4333 
912 |a GBV_ILN_4334 
912 |a GBV_ILN_4335 
912 |a GBV_ILN_4336 
912 |a GBV_ILN_4338 
912 |a GBV_ILN_4393 
912 |a GBV_ILN_4700 
936 b k |a 35.00$jChemie: Allgemeines  |q VZ  |0 106422014  |0 (DE-625)106422014 
951 |a AR 
952 |d 30  |j 2023  |e 2  |b 25  |c 01